2. A circuit is a closed loop, io,...,in-1, in ip of length n ≥ 0. Conservation
of energy is a condition on the k x k matrix V to the effect that, on each circuit the sum is zero
V(i0, i1) + V(i1, 12) + ··· +V(in-1, 0) = 0.
A matrix satisfying this condition is called conservative. Show that each conservative matrix is skew- symmetric. Deduce that the set of conservative matrices is a vector space, closed under vector-space op- erations. Exhibit a 3 x 3 skew-symmetric matrix that is not conservative. A skew-symmetric matrix of the form V(i,j) = a;a; is called additive. Prove that every conservative matrix is additive. What is the dimension of the vector space of conservative 6 x 6 matrices?
The following exercises refer to the linear model for the voltages in which E(Y1j) = a; -a; is conservative. The data is as follows:
Electrolyte O
Mg
Zn
Fe
Pb
Cu
Mg Zn
0.0
0.414
0.807
0.876
1.291
-0.414
0.0
0.429
0.533
0.886
225
Fe
-0.807
-0.429
0.0
0.043
0.377
Pb
-0.876
-0.533
-0.043
0.0
0.271
Cu
-1.291
-0.886
-0.377
-0.271
0.0
Electrolyte A
Mg
0.0
0.247
0.856
1.051
1.402
Zn
-0.247
0.0
0.434
0.521
0.867
Fe
-0.856
-0.434
0.0
0.058
0.443
Pb
-1.051
-0.521
-0.058
0.0
0.374
Cu
-1.402
-0.867
-0.443
-0.374
0.0
Electrolyte K
Mg
0.0
0.443
0.895
0.973
1.281
3228
Zn
-0.443
0.0
0.477
0.503
0.856
Fe
-0.895
-0.477
0.0
0.107
0.432
Pb
-0.973
-0.503
-0.107
0.0
0.392
Cu
-1.281
-0.856
-0.432
-0.392
0.0
(a) For a single kx k table, obtain an expression for the least-squares estimate of a = (a1,...,05). Use this formula to compute â for each of the three electrolytes. Explain why (a1,..., as) and (a1,...,05) + (c, c, c, c, c) are equivalent as parameter points in the model.
(b) Assess the evidence for and against the hypothesis that the vector of potentials is constant across elec- trolytes. That is to say, fit the linear model in which the potentials are constant across electrolytes, and compare the fit with the model in which a varies from one electrolyte to another. Obtain the relevant sums of squares, their degrees of freedom, and compute the appropriate F-statistic.
(c) Discuss briefly the arguments for and against analysis of these data by linear models after transformation.
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